Alkali-Halide Scintillators

Selector guide for alkali halide scintillators.  
Physical Properties of Alkali Halide Scintillators

Detector Nomenclature GuideNaI(Tl)
The necessity to use NaI(Tl) crystals in sealed units is counterbalanced by the fact that they have the greatest light output among all the scintillators and a convenient emission range coinciding with a maximum efficiency of photomultipliers with bialkali photocatodes. Moreover, large-size NaI(Tl) crystals can be produced at a low cost.

 CsI(Na)
CsI(Na) is a good alternative for NaI(Tl) in many standard applications because it has a high light output (85% of that of NaI(Tl)), the emission in a blue spectral region coinciding with the maximum sensitivity of the most popular PMT with bialkali photocatodes, and hygroscopicity substantially lower than that of NaI(Tl).

 CsI(Tl)
Since the maximum of emission spectrum is at 550 nm, photodiodes can be used to detect the emission. Because a scintillator-photodiode pair can be used, it is possible to reduce significantly the size of the detection system, to do without a high-voltage power supply, and to use the detection system in magnetic fields.

 CsI(CO3)
We offer a new scintillation material, CsI(CO3). The light output in gamma-excitation is 60% that of NaI(Tl). The decay time varies from 1.4 to 3.4 ms depending on the dopant concentration. These characteristics allow CsI(CO3) to be used in combination with other scintillators in phoswich detectors. CsI(CO3) has an afterglow of 0.05% after 5 ms.

 Undoped CsI
The decay time is ~10 ns. Undoped CsI can be effectively used for experiments in medium- and high-energy physics.

 LiF(W)
The absorption of thermal neutrons in Li-based crystals proceeds according to the following reaction:
6Li + n -> 4He + 3H + Q
Therefore, the thermal neutrons can be detected against the natural background using the amplitude discrimination. The lithium nuclei number per unit volume for LiF(W) is greater than that in LiI(Eu) by a factor of 3.3.

    

Selector guide for alkali halide scintillators.

Material

Important properties

Applications comments

  NaI(Tl)

  Very high light output, good energy resolution

General scintillation counting, monitoring, health physics, environmental high temperature use

  CsI(Tl)

Non-hygroscopic, rugged, long wavelength emission

Particle- & high energy physics, general detection, photodiode readout, phoswiches

CsI(Na)

High light output, rugged

Geophysical

CsI(pure)

Fast, non-hygroscopic, radiation hard

High energy physics (calorimetry)

CsI(CO3)

Medium decay time, low afterglow

gamma-detection, phoswiches

LiF(W)

High neutron cross-section

Thermal neutron detection

LiI(Eu)

High neutron cross-section, high light output

Thermal neutron detection and spectroscopy

     

Physical Properties of Alkali Halide Scintillators

    

NaI(Tl)

CsI(Na)

CsI(Tl)

CsI
(undoped)

CsI(CO3)

LiF(W)

6LiI(Eu)

Density [g/cm3]

3.67

4.51

4.51

4.51

4.51

2.64

4.08

Melting point [K]

924

894

894

894

894

1133

719

Thermal expansion coefficient [K-1]

47.4x106

49x106

49x106

49x106

49x106

37x106

40x106

Cleavage plane

<100>

none

none

none

none

<100>

<100>

Hardness (Mho)

2

2

2

2

2

3

2

Hygroscopic

yes

yes

slightly

slightly

yes

no

very

Wavelength of emission maximum [nm]

415

420

550

310

405

430

470

Refractive index at emission maximum

1.85

1.84

1.79

1.95

1.84

1.4

1.96

Light output  [% of NaI(Tl)] (for gamma rays)

100

85

45

5-6

60

3.5

30-35

Primary decay time [ms]

0.23

0.63

1

0.01

2

40

1.4

Afterglow  (after 6 ms) [%]

0.3-5

0.5-5

0.1

 

0.06

   

Lower wavelength cutoff [nm]

300

300

320

260

300

 

425

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